A micromeritics autochem ii 2920 apparatus with a thermal conductivity detector tcd was employed for h 2temperatureprogrammedreduction h 2tpr and no or nh 3temperatureprogrammed desorption no or nh 3tpd experiments. Autochem ii 2920 chemisorption analyzer from micromeritics instrument corporation description the autochem ii 2920 is a fully automated chemisorption analyzer that can provide your laboratory with the ability to conduct a comprehensive array of highly precise studies of chemical adsorption and temperatureprogrammed reactions. Temperature can be controlled from sub ambient 70 c to 1100 c with programmable heating ramps and plateaus. The metal dispersion of cozrp and nizrp was measured using h 2 chemisorption analysis with an autochem ii 2920 instrument micromeritics, usa. Subsequently, the sample was cooled down to rt in he flow. In order to ensure a free oxygen atmosphere, 50 mg of samples were pretreated at 5cmin to 250 c for 1 h in flowing helium 70 mlmin, and then cooled down to 40 c. The micromeritics chemisorb 2720 and 2750 quickly and accurately measure the quantity of adsorbed or desorbed molecules allowing determination of these characteristics. Resources and facilities particles and catalysis research group. Figure s2 automated catalyst characterization system from micromeritics. Autochem 2920 automated catalyst characterization system.
Be able to identify and power up the system, including installation of the operating program. The autochem ii 2920 is a fully automated chemisorption analyzer that can provide your laboratory with the ability to conduct a comprehensive array of highly precise studies of chemical adsorption and temperatureprogrammed reactions. Quartz tubereactors micromeritics quantachrome we provide quartz tubing and quartz reactors for a wide range of laboratory equipment, rigs and characterisation instruments. The percent dispersion calculated from the data collected by the mcctc and mass spectrometer yielded 36%. Autochem solutions from mettler toledo 10,666 views. Enhanced software capabilities, data reduction features, and instrument monitoring microactive for tristar ii plus software the intuitive microactive for tristar ii plus software gives the user the ability to interactively evaluate isotherm data and reduce the time required to obtain surface area and porosity data. The package may be requested directly from micromeritics by fax or phone, by way of our home page, or from your local micromeritics representative. Supporting information for confinement of ultrasmall cuzno x.
The autochem ii 2920 utilizes the dynamic flowing gas technique to perform chemical adsorption analysis of active sites on the surface of particles. Usually the sample is pretreated to reduce the metal oxides present to the base metals. By comparing the sample stream to a reference stream of pure carrier gas, changes in gas composition resulting from reactions in the sample cell can be determined. Micromeritics the asap 2050 xtended pressure sorption analyzer is an easytouse instrument capable of collecting physisorption data in an elevatedpressure environment. The autochem ii 2920 is designed for both laboratory research and product development. Thereafter, samples were heated to 800 c using 5% h. Temperature can be controlled from subambient 70 c to 1100 c with programmable heating ramps and plateaus. Micromeritics asap 2020 and autochem ii 2920 can perform a comprehensive array of highly precise chemical adsorption and temperatureprogrammed reaction studies respectively. For each experiment, the sample was purged in he at 5 cmin up to 350 c to remove physically adsorbed co 2 and h 2o molecules, and was then cooled down to 50 c in he. A catalyst characterization laboratory micromeritics. Autochem ii 2920 advanced operator training instructional goals this course introduces students to advanced chemisorption theory, applications and asap 2920 use with a mass spectrometer. Have regular exposure to an autochem ii in a laboratory environment. Worlds fastest scanning electron microscope with its marketleading phenom desktop scanning electron microscope sem, phenomworld helps customers to stay competitive in a world where critical dimensions are continuously getting smaller.
Micromeritics autochem ii 2920 chemisorption analyzer is a fully automated instrument capable of conducting a comprehensive array of highly precise chemical adsorption and temperatureprogrammed reaction studies. Autochem model 2920 catalyst characterization automated. After the sample has been outgassed, reduced, or otherwise prepared, a steady stream of analysis gas flows through the sample bed and reacts with the active. Phenom semscanning electron microscope micromeritics. Autochem ii 2920 a catalyst characterization laboratory in a single analytical instrument micromeritics autochem ii 2920 chemisorption analyzer is a fully automated instrument capable of conducting a comprehensive array of highly precise chemical adsorption and temperature programmed reaction studies. The autochem ii 2920 is a fully automated chemisorption analyzer that can provide your laboratory with the ability to conduct a comprehensive array of highly precise studies of chemical adsorption. Characterizing catalysts via temperatureprogrammed techniques. Technical courses and programs micromeritics learning center course, autochem ii 2920 supplier. Micromeritics study in different formulation colloidal dispersion are characterized by particles that are too small to be seen in the ordinary microscope. Pelletization of catalysts supported on activated carbon. The instrument enables the researcher to obtain valuable information about the physical properties of catalysts, catalyst support, and. Micromeritics autochem ii 2920 instrument equipped with a mass spectrometer. If the pc experiment is performed at elevated pressures.
It provides all the convenient features you are accustomed to when using windowsbased programs. Micromeritics autochem ii 2920 chemisorption analyzer is a fully automated instrument capable of. After that, the reduced catalyst was cooled to 100 oc and then exposed to 1 atm of 5% h 2ar for 2 h, followed by purging. For pretreatment, 100 mg of calcined catalyst was thermally treated in situ at 473 k under a pure n 2 atmosphere 50 mlmin for 2 h. Autochem ii 2920 datasheet micromeritics automated. This manual describes how to install, operate, and maintain the autochem ii 2920 analyzer. The percent dispersion measured from the data obtained through the mass spectrometer and mcctc produced 36%. Before nh3 adsorption, the fresh sample was heated to 120 c 20 c min1 in 30 ml high pure he flow. T e m p e r a t u r e, c royal society of chemistry. Ito powders inframat advanced materials, usa in a autochem ii 2920 system micromeritics instrument corp.
H2tpr and cotpr experiments were run in a micromeritics autochem ii 2920 instrument equipped with a thermal conductivity detector tcd and a mass spectrometer. Catalytic activity is evaluated by measuring the amounts and types of reactive gas adsorbed. Autochem 2920 automated catalyst characterization system operators manual v4. Tpd measurements were performed in both he and he with 12. The particles of pharmaceutical emulsion and suspension and the fines of powder fall in the range of the optical microscope. Needs and resources required background to successfully complete this course, you must. Micromeritics autochem ii 2920, 2950, 2910, asap 2020, both chemisorption and physiosorption. This microreactor, combined with a mass spectrometer, can also be used to determine product yields and catalytic activity under commercially viable conditions. Eciently engineering cubased oxide by surface embedding of. Syllabus autochem ii 2920 operator training instructional goals this course introduces students to the components, operation, and theory of the autochem ii for surface area and porosity analysis.
Desorption and electrical conductivity studies of indium tin. The chemisorb 2720 makes chemisorption and physisorption analyses affordable for applications in which owning an instrument had once been impractical. Autochem ii 2920 chemisorption analyzer from micromeritics. While retaining many of the design elements of micromeritics popular asap 2020, the asap 2050 analysis manifold is equipped with a pressure transducer capable of operating. Jul 02, 2015 the chemisorption instruments offered by micromeritics can be group into either dynamic adsorption instruments autochem ii 2920, autochem hp 2950, or chemisorb 27202750 or static adsorption instruments with some level of dynamic capability asap 2020 chemi, 3flex chemi, chemisorb htp. Temperatureprogrammed reduction tpr determines the number of reducible species present on the catalyst surface and reveals the temperature at which. The samples were preoxidized in a 10%o2he gas mixture 20 cm 3min at 350 oc for 30 min, cooled to rt in he, purged at rt for 30 min, then heated in 20%h2n2 20 cm.
The autochem ii 2920 is a highresolution up to 10 data points per second, fully automated instrument that can be programmed to perform a userdefined sequence of pretreatment and analytical tasks. H 2tpd measurements were obtained using a micromeritics autochem ii 2920 instrument. Quartz tubereactors micromeritics quantachrome oxford. Equipped with many of the features of micromeritics autochem ii 2920, the autochem hp is suitable for a variety of applications including fuel cell and hydrogen storage research. The autochem is a fully automated chemisorption analyzer that can conduct a comprehensive array of highly precise studies of chemical adsorption chemisorption and temperatureprogrammed reactions. A pulse chemisorption analysis figure 1 determines active surface area, percent metal.
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